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Vinyl copper lithium.
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A gilman reagent is a lithium and copper diorganocopper reagent compound r 2 culi where r is an alkyl or aryl these reagents are useful because unlike related grignard reagents and organolithium reagents they react with organic halides to replace the halide group with an r group the corey house reaction such displacement reactions allow for the synthesis of complex products from.
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A colorless or white solid it is encountered mainly as a solution in tetrahydrofuran thf.
5 the addition of grignard reagents to alkynes is facilitated by a catalytic amount of copper halide.
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The use of li 2 cucl 4 rather than simple copper i halide salts cux improves yields of these coupling reactions.
A very popular and often complementary alternative to the foregoing vinyllithium chemistry is the use of lithium divinyl or diaryl cuprate species r 2 culi which also can be alkylated using primary alkyl bromides or iodides but often only in the presence of various additives typically a stabilizing phosphine ligand and the correct solvent.
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For example lithium divinylcuprate is alkylated.
Vinyllithium is an organolithium compound with the formula lic 2 h 3.
Vinyl and aryl grignard reagents couple with primary alkyl halides in the presence of a catalytic amount of a copper i halide salt.